[[Thermodynamics]] # Summary * First law: $\Delta U=Q+W$ * Q is heat added W is work done * Internal energy $U$ is the sum of kinetic energy and potential energy. Ideal gas has no internal potential energy, so solely kinetic. * Ideal monatomic gas has formula: $U=\frac{3}{2}Nk_BT=\frac{3}{2}nRT$ * Work done on gas by external pressure: $W=-P\Delta V$ * Negative sign means expansion does negative work on gas. * On a PV graph, integrals are work done, and straight lines are isotherms. * Four special processes: * Isovolumeric $W = 0$ * Isothermic $\Delta U = 0$ For an ideal gas * Isobaric $W=-P\Delta V$ * Adiabatic $Q=0$