630 B
630 B
Summary
- First law:
\Delta U=Q+W - Q is heat added W is work done
- Internal energy
Uis the sum of kinetic energy and potential energy. Ideal gas has no internal potential energy, so solely kinetic. - Ideal monatomic gas has formula:
U=\frac{3}{2}Nk_BT=\frac{3}{2}nRT - Work done on gas by external pressure:
W=-P\Delta V - Negative sign means expansion does negative work on gas.
- On a PV graph, integrals are work done, and straight lines are isotherms.
- Four special processes:
- Isovolumeric
W = 0 - Isothermic
\Delta U = 0For an ideal gas - Isobaric
W=-P\Delta V - Adiabatic
Q=0
- Isovolumeric